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President of the Poor Law Board
| Name | Entered office | Left office | Party | Notes |
|---|---|---|---|---|
| Charles Buller | 23 July 1847 | 1 January 1849 | Whig | |
| Matthew Talbot Baines | 1 January 1849 | 21 February 1852 | Whig | |
| Sir John Trollope | 1 March 1852 | 17 December 1852 | Conservative | |
| Matthew Talbot Baines | 30 December 1852 | 13 August 1855 | Whig | |
| Edward Pleydell-Bouverie | 13 August 1855 | 21 February 1858 | Whig | |
| Thomas Sotheron Estcourt | 6 March 1858 | 7 March 1859 | Conservative | |
| Earl of March | 7 March 1859 | 11 June 1859 | Conservative | |
| Thomas Milner Gibson | 24 June 1859 | 9 July 1859 | Liberal | |
| Charles Pelham Villiers | 9 July 1859 | 26 June 1866 | Liberal | |
| Gathorne Hardy | 12 July 1866 | 21 May 1867 | Conservative | |
| The Earl of Devon | 21 May 1867 | 1 December 1868 | Conservative | |
| George Goschen | 9 December 1868 | 24 March 1871 | Liberal | |
| James Stansfeld | 24 March 1871 | 14 August 1871 | Liberal |
succeeded by office of President of the Local Government Board